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Composition, structure and electrical properties of alumina barrier layers grown in fluoride-containing oxalic acid solutions

September 17, 2008 By: admin Category: Materials Science, Physical Sciences and Engineering

The composition, structure and electrical properties of alumina barrier layers grown by anodic oxidation in F?-containing (FC) and F?-free (FF) oxalic acid solutions were studied using the re-anodizing/dissolution technique, Fourier-transformed infrared and X-ray photoelectron spectroscopy. These results confirmed formation in FC anodizing solutions of films structurally different from ones grown in FF oxalic acid baths. It was found that the barrier layer of FC alumina films is composed of two layers differing in the dissolution rate. These differences are related to the formation in the FC electrolyte of a barrier layer composed of a more microporous outer part and a thin, non-porous and non-scalloped inner part consisting of aluminum oxide and aluminum fluoride.

A. JagminasaEmail:jagmin@ktl.mii.lt?I. Vrublevskyb?J. Kuzmarskyta?V. Jasulaitiena
[a]Institute of Chemistry, A. Gotauto 9, LT-01108 Vilnius, Lithuania;[b]Department of Microelectricals, Belarusian State University of Informatics; Radioelectricals, 6 Brovka Street, Minsk 220013, Belarus

Ceramic and single-crystal (1 – x)PMN–xPT constitutive behavior under combined stress and electric field loading

September 17, 2008 By: admin Category: Materials Science, Physical Sciences and Engineering

Pb(Mg1/3Nb2/3)O3–0.32(PbTiO3), PMN–0.32PT, single crystals have been characterized under combined stress and electric field loading [McLaughlin EA, Liu T, Lynch CS. Relaxor ferroelectric PMN–32%PT crystals under stress and electric field loading: I-32 mode measurements. Acta Mater 2004;52:3849, McLaughlin EA, Liu T, Lynch CS. Relaxor ferroelectric PMN–32%PT crystals under stress, electric field and temperature loading: II-33-mode measurements. Acta Mater 2005;53:4001] [1], [2] and [3]. This approach is extended to PMN–0.26PT single crystals to explore the effect of composition on field driven phase transformations and to PMN–0.32PT ceramic specimens to compare with polycrystalline behavior. Electric displacement and strain were measured as a function of combinations of stress and both unipolar and bipolar electric fields. The single-crystal results indicate that compositions further from the morphotropic phase boundary require higher driving forces for field induced phase transformations. Evidence of these transformations is not apparent in the results from the ceramic specimens.

Kyle G. Webbera?Ruzhong Zuob?Christopher S. LynchcEmail:cslynch@seas.ucla.edu
[a]The George W. Woodruff School of Mechanical Engineering, The Georgia Institute of Technology, Atlanta, GA 30332, USA;[b]Institute of Materials Science, Darmstadt University of Technology, 64287 Darmstadt, Germany;[c]Department of Mechanical; Aerospace Engineering, The University of California Los Angeles, 36-146 Engineering IV, 420 Westwood Plaza, Los Angeles, CA 90095-1597, USA

Crystal structure effect of ferromagnetic electrode on tunneling magnetoresistance

September 17, 2008 By: admin Category: Materials Science, Physical Sciences and Engineering

We show experimentally the effect of the crystal structure of a ferromagnetic (FM) electrode on tunneling magnetoresistance (TMR) by changing only the crystal structure of the bottom FM electrode in a magnetic tunnel junction (MTJ) and observing a significant TMR difference. Co87Fe13 was selected as the bottom FM electrode because the difference in stability between its face-centered cubic (fcc) and body-centered cubic (bcc) structures is very small. This enables us to compare the TMR of MTJs comprising ferromagnetic layers at the same composition but with different crystal structures. We find a significant increase in the TMR when changing from an fcc-Co87Fe13 to bcc-Co87Fe13 bottom FM electrode. The structurally induced TMR enhancement is attributed to a higher s-electron spin polarization for the bcc structure, which was confirmed for bulk Co and Co87.5Fe12.5 by ab initio calculations. These results unambiguously demonstrate the role of crystal structure and the associated electronic structure of FM electrodes in spin-dependent tunneling.

J. Joshua Yanga?A.K. Bengtsona?C.-X. Jia?D. Morgana?Y.A. Chang aEmail:chang@engr.wisc.edu
[a]Department of Materials Science; Engineering; Materials Science Program, University of Wisconsin-Madison, Madison, WI 53706, USA

Chill zone copper with the strength of stainless steel and tailorable color

September 17, 2008 By: admin Category: Materials Science, Physical Sciences and Engineering

We report here on 90 at.% copper 2–4 mm thick castings with fracture strengths up to 1.9 MPa due to the formation of a thick, scratch-resistant nanocrystalline chill-zone next to the copper mold contact surfaces. It is found that the unusually hard nanocrystalline surface layers of thicknesses in the range of 200–300 ?m form when the melt can be undercooled: when the alloy composition is such that the contact surface of the copper mold with the liquid alloy does not serve as a preferred site for crystal nucleation, supercooling of the melt in the chill-zone is possible. These castings are the hardest coppers ever reported to date in macroscopic specimens. They have mechanical strength superior to those of many stainless steels as well as to Cu–Be alloys and of the order of those of Cu-based bulk metallic glasses (BMGs) of similar dimensions. In addition, and unlike in copper-based BMGs, the color and luster can be tailored by elemental additions to vary from copper-like to gold-like.

A.R. YavariaEmail:yavari@ltpcm.inpg.fr?K. Otaa?K. Georgarakisa?A. LeMouleca?F. Charlota?G. Vaughanb?A.L. Greerc?A. Inoued
[a]SIMAP-LTPCM, Institut National Polytechnique de Grenoble, BP 75, Saint Matrin d’Heres campus, Grenoble 38402, France;[b]European Synchrotron Radiation Facility, Grenoble 38042, France;[c]Department of Materials Science; Metallurgy, Cambridge University, Cambridge, UK;[d]Tohoku University, Sendai, Japan

Characterizing the shale gas resource potential of Devonian-Mississippian strata in the Western Canada sedimentary basin: Application of an integrated formation evaluation

September 17, 2008 By: admin Category: Engineering, Energy and Technology, Physical Sciences and Engineering

Devonian-Mississippian strata in the northwestern region of the Western Canada sedimentary basin (WCSB) were investigated for shale gas potential. In the subsurface, thermally mature strata of the Besa River, Horn River, Muskwa, and Fort Simpson formations attain thicknesses of more than 1 km (0.6 mi), encompassing an area of approximately 125,000 km (48,300 mi ) and represent an enormous potential gas resource. Total gas capacity estimates range between 60 and 600 bcf/section. Of particular exploration interest are shales and mudrocks of the Horn River Formation (including the laterally equivalent lower Besa River mudrocks), Muskwa Formation, and upper Besa River Formation, which yield total organic carbon (TOC) contents of up to 5.7 wt.%. Fort Simpson shales seldom have TOC contents above 1 wt.%. Horn River and Muskwa formations have excellent shale gas potential in a region between longitudes 122 degreeW and 123 degreeW and latitudes 59degreeN and 60 degreeN (National Topographic System [NTS] 94O08 to 94015). In this area, which covers an areal extent of 6250 km~2 (2404 mi~2 ), average TOC contents are higher (>3 wt.% as determined by wire-line-log calibrations), and have a stratal thickness of more than 200 m (656 ft). Gas capacities are estimated to be between 100 and 240 bcf/section and possibly greater than 400 tcf gas in place. A substantial percentage of the gas capacity is free gas caused by high reservoir temperatures and pressures. Muskwa shales have adsorbed gas capacities ranging between 0.3 and 0.5 cm~3/g (9.6-16 scf/t) at reservoir temperatures of 60-80degreeC (140-176 degree F), whereas Besa River mudrocks and shales have low adsorbed gas capacities of less than 0.01 cm13/g [0.32 scf/t; Liard Basin region) because reservoir temperatures exceed 130 degreeC (266degreeF). Potential free gas capacities range from 1.2 to 9.5 cm~3/g (38.4 to 304 scf/t) when total pore volumes (0.4-6.9%) are saturated with gas. The mineralogy has a major influence on total gas capacity. Carbonate-rich samples, indicative of adjacent carbonate platform and embayment successions, commonly have lower organic carbon content and porosity and corresponding lower gas capacity (< 1 % TOC and <1% porosity). Seaward of the carbonate Slave Point edge, Muskwa and lower Besa River mudrocks can be both silica and TOC rich (up to 92% quartz and 5 wt.% TOC) and most favorable for shale gas reservoir exploration because of possible fracture enhancement of the brittle organic- and siliceous-rich facies. However, an inverse relation between silica and porosity in some re- gions implies that zones with the best propensity for fracture completion may not provide optimal gas capacity, and a balance between favorable reservoir characteristics needs to be sought.

Daniel J. K. Ross?R. Marc Bustin
Department of Earth and Ocean Sciences, University of British Columbia, 6339 Stores Road. Vancouver. British Columbia. Canada V6T 1Z4; Department of Geological Sciences, University of British Columbia, 6339 Stores Road. Vancouver, British Columbia Canada. V6T 1Z4

Connecting worlds: The translation of international auditing standards into post-Soviet audit practice

September 17, 2008 By: admin Category: Psychology, Social Sciences and Humanities

This paper analyses the use and circulation of international auditing standards within a large post-Soviet Russian audit firm, as it faces up to the challenges of international harmonisation. It describes this process as one of “connecting worlds” and translation. In a detailed field study based investigation, it traces various attempts to articulate and link Soviet and post-Soviet worlds, old and new imagined audit worlds. The paper underscores the fragile and precarious nature of international standardisation projects. It shows how ideals of audit universalism and international comparability become enmeshed in, and challenged by, global divisions of audit labour, problems and practices of power and exclusion, and struggles for intra-professional distinction, which in turn undermine as well as promote the connecting of worlds through standards.

Andrea Mennicken aEmail:a.m.mennicken@lse.ac.uk
[a]London School of Economics; Political Science, Department of Accounting; Centre for Analysis of Risk; Regulation, Houghton Street, London WC2A 2AE, UK

CEO TRANSFORMATIONAL LEADERSHIP: THE ROLE OF GOAL IMPORTANCE CONGRUENCE IN TOP MANAGEMENT TEAMS.

September 16, 2008 By: admin Category: Decision Sciences, Social Sciences and Humanities

Using data from 94 top management teams, we found that dyadic goal importance congruence between CEOs and vice presidents (VPs) partially mediated the relationship of CEO transformational leadership with individual VPs;attitudes, but not their performance. However, finer-grained analyses suggested it may be higher VP perceptions of goal importance, rather than the exact correspondence between CEO and VP goal importance ratings, that are associated with both CEO transformational leadership and VP attitudes. At the organizational level, CEO transformational leadership was positively related to within-team goal importance congruence, which in turn was positively related to organizational performance.

Colbert, Amy E.1 amy-colbert@uiowa.edu?Kristof-Brown, Amy L.2 amy-kristof-brown@uiowa.edu?Bradley, Bret H.3?Barrick, Murray R.4 mbarrick@mays.tamu.edu
[1]Assistant Professor in the Department of Management and Organizations at the University of Iowa;[2]Weissman/Sinicropi Research Fellow at the Henry B. Tippie College of Business, Univerisity of Iowa;[3]Doctoral Candidate in Organizational Behavior at the Henry B. Tippie College of Business, University of Iowa;[4]Head of the Management Department and the Paul M. and Rosalie Robertson Chair in Business at the Mays Business School, Texas A&M University

Corporate transparency, financial development; the allocation of capital: Empirical evidence

September 16, 2008 By: admin Category: Economics, Econometrics and Finance, Social Sciences and Humanities

There is controversy regarding the role of financial development in promoting economic growth. Lucas (1988) suggests that the role of financial intermediation in economic growth has been very badly over-stressed in the popular; professional discussion. Levine et al. (2000), on the other hand, show that in a cross-country setting the exogenous component of financial intermediary development is positively; robustly linked to economic growth. Although empirical methodologies to investigate the finance-growth nexus have been refined, there is a lack of understanding about the exact mechanisms through which the financial system could affect economic performance in the real sector. Wurgler (2000) investigates one such mechanism of economic growth: whether capital is allocated efficiently. He then empirically shows that countries with well-developed financial architecture improve capital allocation. This article extends Wurgler (2000) by investigating the role of an important economic institution, the financial reporting system, on the efficiency of capital allocation. Financial reporting provides the primary source of independently verified information to the capital providers about the performance of managers; facilitates efficient resource allocation decisions. Results show that financial transparency is positively; significantly related to capital allocation efficiency. Further, this result holds after controlling for the impact of stock price synchronicity, state-owned enterprises; investor protection rights. 2008 Accounting Foundation.

Habib, A.Email:ahsan.habib@aut.ac.nz
Department of Accounting, Auckland University of Technology

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